Detailed Kinetic Modeling Study of n-Pentanol Oxidation

نویسندگان
چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Detailed kinetic modeling of ethane oxidation

A detailed chemical kinetic model has been developed for ethane oxidation that is applicable over a wide range of temperatures and pressures. This model incorporates the results of recent ab initio studies of the important lowtemperature pathways of the C2H5 + O2 reaction as well as several C2H6 + RO2 abstraction reactions. These results change significantly the nature of the chain-branching re...

متن کامل

Kinetics and Mechanism of Oxidation of n-Pentanol by Tetramethylammonium Fluorochromate

The oxidation of n-pentanol by tetramethylammonium fluorochromate in acidic solution wasstudied using spectrophotometric technique. The reaction was arranged to be under pseudo firstorderconditions respect to the oxidant. A Michaelis-Menten type kinetic was observed respect tothe substrate. The reaction is catalyzed by hydrogen ions. Dependences of the reaction rates ontemperature and different...

متن کامل

N-Bromosaccharin oxidation of some aldoses: A kinetic study

Kinetics of oxidation of some aldoses viz. Dribose, Dxylose, L – arabinose and Dglucose by Nbromosaccharin in aqueous acetic medium in the presence of mercuric acetate as a scavenger for Br-, exhibits first order dependence in [NBSA] and [HC1O4]. The order with respect to aldose varies from 1 to 0. The reaction rate is retarded by the addition of saccharin. Effect of variation of composition of...

متن کامل

Kinetic Modeling of Methyl Formate Oxidation

A kinetic model for methyl formate oxidation is generated using our open-source Reaction Mechanism Generator (RMG) software, supplemented with high level quantum calculations and transition state theory (TST). New rate coefficients are calculated for the decomposition pathways of methyl formate, methoxy-formyl (CH3OC ·O), and formyloxy-methyl (C H2OCHO), and hydrogen abstractions from methyl fo...

متن کامل

A comprehensive experimental and detailed chemical kinetic modelling study of 2,5-dimethylfuran pyrolysis and oxidation.

The pyrolytic and oxidative behaviour of the biofuel 2,5-dimethylfuran (25DMF) has been studied in a range of experimental facilities in order to investigate the relatively unexplored combustion chemistry of the title species and to provide combustor relevant experimental data. The pyrolysis of 25DMF has been re-investigated in a shock tube using the single-pulse method for mixtures of 3% 25DMF...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Energy & Fuels

سال: 2012

ISSN: 0887-0624,1520-5029

DOI: 10.1021/ef3012596